|
|
H+ + H2O + 2,5-diamino-6-ribosylamino-4(3H)-pyrimidinone_5'-phosphate <=> 5-amino-6-(5-phospho-D-ribosylamino)uracil + NH3
|
3.5.4.26
diaminohydroxyphosphoribosylaminopyrimidine deaminase
|
–
|
|
BRENDA:
BR26118
KEGG:
R03459
MetaCyc:
RIBOFLAVINSYNDEAM-RXN
|
|
|
|
5-amino-2,6-dioxy-4-(5'-phosphoribitylamino)pyrimidine + H2O <=> 5-amino-6-ribitylamino-2,4(1H,3H)-pyrimidinedione + phosphate
|
3.1.3.104
5-amino-6-(5-phospho-D-ribitylamino)uracil phosphatase
|
–
|
|
BRENDA:
BR51773
KEGG:
R07280
MetaCyc:
RIBOPHOSPHAT-RXN
SABIO-RK:
8920
|
|
|
|
5-amino-2,6-dioxy-4-(5'-phosphoribitylamino)pyrimidine + NADP+ <=> 5-amino-6-(5-phospho-D-ribosylamino)uracil + NADPH + H+
|
1.1.1.193
5-amino-6-(5-phosphoribosylamino)uracil reductase
|
–
|
|
BRENDA:
BR29246
KEGG:
R03458
MetaCyc:
RIBOFLAVINSYNREDUC-RXN
|
|
|
|
S-adenosyl-L-methionine + reumycin <=> toxoflavin + S-adenosyl-L-homocysteine + H+
|
2.1.1.349
toxoflavin synthase
|
–
|
|
BRENDA:
BR52482
KEGG:
R12158
MetaCyc:
RXN-19529
|
|
|
|
5-amino-6-ribitylamino-2,4(1H,3H)-pyrimidinedione + glycine <=> 1,6-didemethyltoxoflavin
|
not assigned
|
–
|
|
MetaCyc:
RXN-19531
|
|
|
|
H2O + GTP <=> H+ + diphosphate + 2,5-diamino-6-ribosylamino-4(3H)-pyrimidinone_5'-phosphate + formate
|
3.5.4.25
GTP cyclohydrolase II
|
–
|
|
BRENDA:
BR26117
KEGG:
R00425
MetaCyc:
GTP-CYCLOHYDRO-II-RXN
SABIO-RK:
880
|
|
|
|
S-adenosyl-L-methionine + 1,6-didemethyltoxoflavin <=> reumycin + S-adenosyl-L-homocysteine + H+
|
2.1.1.349
toxoflavin synthase
|
–
|
|
BRENDA:
BR52481
KEGG:
R12157
MetaCyc:
RXN-19530
|
|